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【高频词句】
1.price list and instruction价格单和说明书
2.establish business relationship建立贸易关系
Phosphotungstic acid (PHA) supported on magnetic nanoparticles Fe3O4 coated by SiO2 (Fe3O4@SiO2/PHA) was prepared and employed for the synthesis of 5-(hydroxymethyl)furfural (HMF) from glucose. The as-prepared catalyst was characterized by infrared spectroscopy (IR) and powder X-ray diffraction (XRD). It was found that the supported catalyst Fe3O4@SiO2/PHA exhibited similar catalytic activity to that of PHA. The effects of such reaction variables as the amount of PHA, reaction solvent, temperature and time were studied in detail. The yield of HMF at 30.4% was observed at 130 oC for 3 h in N, N-dimethylformamide. The supported catalyst was recovered after the reaction and reused without further treatment. No significant change in activity was observed at the initial 4 cycles, in which the yield of HMF changed in a small range from 28.7 to 30.4%.